The Match Official appointments for Round 5 of the Australian Championship have been confirmed by Football Australia.
For the list of appointments from 7-9 November see below.
| Sydney United 58 v Wests APIA FC | Friday 7 November 2025 | |||
| Sydney United Sports Centre | 7:35 PM (Local) | 7:35 PM (AEDT) | ||
| Referee | Jack Powers | Assistant Referee 2 | Lucy Hungerford | |
| Assistant Referee 1 | Aaron Bloch | Fourth Official | Jock Quartermain | |
| Sydney Olympic v Moreton City Excelsior | Saturday 8 November 2025 | |||
| Jubilee Oval | 1:00 PM (Local) | 1:00 PM (AEDT) | ||
| Referee | Jock Quartermain | Assistant Referee 2 | Seb Ruskin | |
| Assistant Referee 1 | Alessandro Llana | Fourth Official | Matt Staples | |
| South Melbourne FC v Broadmeadow Magic | Saturday 8 November 2025 | |||
| Lakeside Stadium | 3:15 PM (Local) | 3:15 PM (AEDT) | ||
| Referee | Eric Saba | Assistant Referee 2 | Luke Gennimatas | |
| Assistant Referee 1 | Patrick Teleki | Fourth Official | Brodie Merchant | |
| South Hobart v Marconi Stallions | Sunday 9 November 2025 | |||
| South Hobart Oval | 1:00 PM (Local) | 1:00 PM (AEDT) | ||
| Referee | Brenton Kopra | Assistant Referee 2 | Thomas Mace | |
| Assistant Referee 1 | Joshua Berry | Fourth Official | Nathan Coad | |
| Preston Lions v Canberra Croatia | Sunday 9 November 2025 | |||
| Genis Steel Stadium | 1:00 PM (Local) | 1:00 PM (AEDT) | ||
| Referee | Brodie Merchant | Assistant Referee 2 | William Samsa | |
| Assistant Referee 1 | Lance Greenshields | Fourth Official | Eric Saba | |
| Heidelberg United v Wollongong Wolves | Sunday 9 November 2025 | |||
| Olympic Park (Village) | 1:00 PM (Local) | 1:00 PM (AEDT) | ||
| Referee | Daniel Cook | Assistant Referee 2 | Marc Tito | |
| Assistant Referee 1 | Peter Jaworski | Fourth Official | Tom Dale | |
| MetroStars SC v Bayswater City | Sunday 9 November 2025 | |||
| T.K. Shutter Reserve | 4:00 PM (Local) | 4:30 PM (AEDT) | ||
| Referee | Declan Woods | Assistant Referee 2 | Cameron Wright | |
| Assistant Referee 1 | Nick Elagin | Fourth Official | Tom Brinkworth | |
| Avondale v NWS Spirit | Sunday 9 November 2025 | |||
| Avengers Park | 4:30 PM (Local) | 4:30 PM (AEDT) | ||
| Referee | Jack Morgan | Assistant Referee 2 | Matthew Harris | |
| Assistant Referee 1 | Benjamin Lepileo | Fourth Official | Pouya Ghardirian | |